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作者郝一男,刑东,潘艳飞,王喜明,姚利宏（2019）在《Structure and Performance of Ce-nano PO43-/ZrO2 Solid Acid Catalyst for Producing Biodiesel》一文中研究指出：The biodiesel prepared from Xanthoceras Sorbiflia Bunge Oil catalyzed by Ce doped nano PO43-/ZrO2 was investigated. A maximum biodiesel yield of 91.83% was achieved at the concentration of Ce3+ up to 0.1 mol/L, calcination temperature 500 °C, calcination time 3.0 h, and the concentration of phosphoric acid of 3.5 mol/L. Ce-nano PO43-/ZrO2 catalyst activities were correlated with the observed physico-chemical characteristics derived from scanning electron microscopy（SEM）, FT-infrared（FT-IR）, X-ray diffraction（XRD）, thermogravimetric（TG） and Brunauer-Emmett-Teller（BET） analysis. The delayed crystallization of ZrO2 made surface oxides have more defects which were beneficial to the adsorption of PO43- by the concentration increment of Ce3+. The chemical composition of synthesized biodiesel was confirmed by gas chromatography（GC）. The characteristics of Xanthoceras Sorbiflia Bunge oil were found within the optimal range in accordance with Chinese No. 0 diesel standard as a substitute diesel fuel.
Abstract
The biodiesel prepared from Xanthoceras Sorbiflia Bunge Oil catalyzed by Ce doped nano PO43-/ZrO2 was investigated. A maximum biodiesel yield of 91.83% was achieved at the concentration of Ce3+ up to 0.1 mol/L, calcination temperature 500 °C, calcination time 3.0 h, and the concentration of phosphoric acid of 3.5 mol/L. Ce-nano PO43-/ZrO2 catalyst activities were correlated with the observed physico-chemical characteristics derived from scanning electron microscopy（SEM）, FT-infrared（FT-IR）, X-ray diffraction（XRD）, thermogravimetric（TG） and Brunauer-Emmett-Teller（BET） analysis. The delayed crystallization of ZrO2 made surface oxides have more defects which were beneficial to the adsorption of PO43- by the concentration increment of Ce3+. The chemical composition of synthesized biodiesel was confirmed by gas chromatography（GC）. The characteristics of Xanthoceras Sorbiflia Bunge oil were found within the optimal range in accordance with Chinese No. 0 diesel standard as a substitute diesel fuel.
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论文作者分别是来自Chinese Journal of Structural Chemistry的郝一男,刑东,潘艳飞,王喜明,姚利宏，发表于刊物Chinese Journal of Structural Chemistry2019年03期论文，是一篇关于,Chinese Journal of Structural Chemistry2019年03期论文的文章。本文可供学术参考使用，各位学者可以免费参考阅读下载，文章观点不代表本站观点，资料来自Chinese Journal of Structural Chemistry2019年03期论文网站，若本站收录的文献无意侵犯了您的著作版权，请联系我们删除。