:GO/PVA nanocomposites with significantly enhanced mechanical properties through metal ion coordination论文

:GO/PVA nanocomposites with significantly enhanced mechanical properties through metal ion coordination论文

本文主要研究内容

作者(2019)在《GO/PVA nanocomposites with significantly enhanced mechanical properties through metal ion coordination》一文中研究指出:In this study, a simple and efficient way is demonstrated to create strong interfacial interaction between graphene oxide(GO) filler and poly(vinyl alcohol)(PVA) matrix through metal ion coordination. The coordination bonding provides efficient load transfer during the tensile process, and enhances the mechanical properties of the nanocomposites significantly. After being coordinated with Cu(Ⅱ) ions, GO/PVA composites show much higher Young’s moduli and yield stresses than pure PVA and noncoordinated GO/PVA. UV–vis and FTIR spectra are performed to confirm the successful coordination between GO and PVA. Ethylene diamine tetraacetic acid disodium salt(EDTA-2 Na) is used to confirm the important role of coordination in enhancing the composites. This research provides a new approach to manufacture polymer-matrix nanocomposites with significantly improved mechanical performances.

Abstract

In this study, a simple and efficient way is demonstrated to create strong interfacial interaction between graphene oxide(GO) filler and poly(vinyl alcohol)(PVA) matrix through metal ion coordination. The coordination bonding provides efficient load transfer during the tensile process, and enhances the mechanical properties of the nanocomposites significantly. After being coordinated with Cu(Ⅱ) ions, GO/PVA composites show much higher Young’s moduli and yield stresses than pure PVA and noncoordinated GO/PVA. UV–vis and FTIR spectra are performed to confirm the successful coordination between GO and PVA. Ethylene diamine tetraacetic acid disodium salt(EDTA-2 Na) is used to confirm the important role of coordination in enhancing the composites. This research provides a new approach to manufacture polymer-matrix nanocomposites with significantly improved mechanical performances.

论文参考文献

  • [1].Synthesis and Structural Characterization of [Co(Q)2(H2O)2](Q=8-Hydroxyquinoline Ion)[J]. 胡长文,王春秀,李晖,牛学丽,潘万龙,龚云.  Journal of Beijing Institute of Technology(English Edition).2006(02)
  • [2].Synthesis of Five-coordinated Anionic Tin(Ⅳ) Complexes and Crystal Structure of [(i-Pr)2NH2][PhSn( μ2-SCH2COO)2][J]. ZHONG Gui-yun,SONG Hai-bin, XIE Qing-lan and SUN Li-juan ** Institute of Elemento-Organic Chemistry,Nankai University,Tianjin 300071,P. R. China.  Chemical Research in Chinese Universities.2004(03)
  • [3].Formation of six-coordinated silicon in calcium phosphosilicate xerogels assisted by polyols at low temperature and pressure[J]. Ai-Ling Li,Yan-Ping Ma,Dong Qiu.  Chinese Chemical Letters.2015(06)
  • [4].Synthesis, Properties and Crystal Structure of Seven-coordinated Organotin Complex [nBu2Sn(OOCC5H4N-2)2(H2O)][J]. 尹汉东,王传华,马春林,王勇.  Chinese Journal of Chemistry.2002(12)
  • [5].Infinite Three-Dimensional Coordination Polymers: Synthesis and Structures of [Cd (4,4’-bpy)2(H2O)2]n(pic)2n,[Zn (4,4’-bpy)2(H2O)2]n(pic)2n(H2O)2n, and [Zn (4,4’-bpy)2(H2O)2]n(4,4’-bpy)n(H2O)n(pic)2n[J]. Fu Pei LIANG~1;Zi Lu CHEN~1;Rui Xiang HU~1;Hong LIANG~1;Zhao Hui ZHOU~2 (1 Department of Chemistry. Guangxi Normal University: Guilin 541004 2 Department of Chemistry. Xiamen University. Xiamen 361005).  Chinese Chemical Letters.2000(04)
  • [6].Crystal Structure of the Samarium Chlorosilicate Sm3(SiO4)2Cl[J]. CHI Li-Sheng; ZHOU Liu-Fang; CHEN Hua-Yang;ZHANG Hong-Hui; HUANG Jin-Shun(State Key Laboratory of Structural Chemistry, Fujain Institute of Research onthe Structure of Matter, the Chinese Academy of Sciences, Fuzhou 35002)(Chemistry Department, Fujian Tea.  结构化学.1997(03)
  • [7].CRYSTAL STRUCTURE OF SEVEN-COORDINATE TRIPODAL MANGANESE(Ⅱ) COMPLEX[J]. Shao Hua GOU Zheng XU and Xiao Zeng YOU Coordination Chemistry Institute, Hanjing Univeraity, Nanjing 210008 Kai Bei YU Chengdu Center of Analysis and Determinmtion, Academia Sinioa, Chengdu 610015.  Chinese Chemical Letters.1991(10)
  • [8].Study of Resolution of dl-Amino Acids with Acrylate Type of LigandE Exchange Ghiral Resins[J]. He Binglin(Ho Pinglun) and Jin Renhua(Institute of Polymer Chemistry, Nankai University, Tianjin).  Chemical Journal of Chinese Universities.1988(01)
  • [9].CRYSTAL AND MOLECULAR STRUCTURE OF TETRACHLORO-BIS[BIS(2-ETHYLHEXYL)-SULFIDE]-PLATINUM(IV)[J]. Yang Qingchuan Tang YouqiInstitute of Physical Chemistry, Peking University, BeijingWang Hanzhang Zhu QinhuaDepartment of Chemistry, Suzhou University, Suzhou.  结构化学.1988(02)
  • [10].Synthesis and Structure of Dibenzoyl-bissemicarbazone Neodymium(Ⅲ) Perchlorate[J]. Huang Ling, Huang Chunhui and Xu Guangxian (Research Centre of Rare Earth Chemistry, Beijing University, Beijing)Zheng Qitai and He Cunheng (Institute of Pharmacology, CJanese Academy of Medical Science, Beijing).  Chemical Journal of Chinese Universities.1989(04)
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