本文主要研究内容
作者王博(2019)在《不锈钢复合过滤膜的制备及其乳化液分离性能研究》一文中研究指出:传统油水乳化液分离方法需要外加驱动力,过程繁杂,研究新型乳化液分离技术势在必行,膜分离技术的快速发展,为油水分离提供了便捷。本文采用简单化学氧化聚合法、化学沉积法和低温水热合成法,在不锈钢网表面构建粗糙结构,制备超亲水/水下超疏油涂层不锈钢网,用于油水分离和水包油型乳化液分离。采用化学氧化聚合法在不锈钢网表面聚合生长微纳米聚吡咯涂层,在空气中具有超双亲性,水下三氯甲烷接触角为158.5°±1.5°,经强酸、强碱和饱和食盐水溶液浸泡24 h后,仍保持良好水下超疏油性,涂层稳定性好。在重力下,可以有效地从各种油水混合物中分离出油或水,分离效率大于97%,在各种恶劣环境下具有良好的可循环利用性,30次循环后分离效率为95.8%。FeCl3作为氧化剂效果最佳,(NH4)2S2O8可快速大量制备涂层不锈钢网,适用于批量生产。用化学沉积法制备了均匀氧化钨涂层,通过浸涂二氧化钛溶胶,煅烧得到较高强度WO3/TiO2复合涂层不锈钢网,具有水下超疏油性、低粘附性,20 kPa压力下摩擦,仍保持良好水下疏油性和较高分离效率。对不同种类水包油型乳化液具有很好分离效果,分离速度较快,重力下水通量为200 L·m-2·h-1左右,0.1 MPa下水通量超过1200 L·m-2·h-1,分离效率大于98.5%,多次循环使用,分离效率大于96%。复合涂层具有良好防污塞性能,在水通量下降情况下,用酒精冲洗后,水通量可恢复到初始值。采用低温水热合成法制备氧化锌涂层,用TiO2溶胶煅烧加固,制备出超亲水/水下超疏油ZnO/TiO2复合涂层不锈钢网,水下氯仿接触角为154.5°±0.8°。TiO2在ZnO涂层表面形成一层致密氧化膜,提升了涂层耐酸、碱腐蚀性能,经酸碱溶液浸泡12小时,仍具有较好水下疏油性能。对不同种类水包油型乳化液都有较好分离效果,分离速度快,重力下水通量为500 L·m-2·h-1左右,0.05 bar下水通量超过1500 L·m-2·h-1,分离效率大于98.5%。乳化液酸碱性对分离效率影响较小,但经酸碱浸泡处理12小时后,分离效率减小,碱性浸泡后减小幅度大于酸性条件。复合涂层对血液中高血脂具有一定的分离效果。综上,PPy、WO3/TiO2和ZnO/TiO2复合涂层不锈钢网,制备工艺简单、成本低廉、无污染,为高效、绿色、快速分离油水混合物和水包油型乳化液提供有效方法,其中ZnO/TiO2复合涂层不锈钢网为实现血脂分离提供基础研究。
Abstract
chuan tong you shui ru hua ye fen li fang fa xu yao wai jia qu dong li ,guo cheng fan za ,yan jiu xin xing ru hua ye fen li ji shu shi zai bi hang ,mo fen li ji shu de kuai su fa zhan ,wei you shui fen li di gong le bian jie 。ben wen cai yong jian chan hua xue yang hua ju ge fa 、hua xue chen ji fa he di wen shui re ge cheng fa ,zai bu xiu gang wang biao mian gou jian cu cao jie gou ,zhi bei chao qin shui /shui xia chao shu you tu ceng bu xiu gang wang ,yong yu you shui fen li he shui bao you xing ru hua ye fen li 。cai yong hua xue yang hua ju ge fa zai bu xiu gang wang biao mian ju ge sheng chang wei na mi ju bi ge tu ceng ,zai kong qi zhong ju you chao shuang qin xing ,shui xia san lv jia wan jie chu jiao wei 158.5°±1.5°,jing jiang suan 、jiang jian he bao he shi yan shui rong ye jin pao 24 hhou ,reng bao chi liang hao shui xia chao shu you xing ,tu ceng wen ding xing hao 。zai chong li xia ,ke yi you xiao de cong ge chong you shui hun ge wu zhong fen li chu you huo shui ,fen li xiao lv da yu 97%,zai ge chong e lie huan jing xia ju you liang hao de ke xun huan li yong xing ,30ci xun huan hou fen li xiao lv wei 95.8%。FeCl3zuo wei yang hua ji xiao guo zui jia ,(NH4)2S2O8ke kuai su da liang zhi bei tu ceng bu xiu gang wang ,kuo yong yu pi liang sheng chan 。yong hua xue chen ji fa zhi bei le jun yun yang hua wu tu ceng ,tong guo jin tu er yang hua tai rong jiao ,duan shao de dao jiao gao jiang du WO3/TiO2fu ge tu ceng bu xiu gang wang ,ju you shui xia chao shu you xing 、di nian fu xing ,20 kPaya li xia ma ca ,reng bao chi liang hao shui xia shu you xing he jiao gao fen li xiao lv 。dui bu tong chong lei shui bao you xing ru hua ye ju you hen hao fen li xiao guo ,fen li su du jiao kuai ,chong li xia shui tong liang wei 200 L·m-2·h-1zuo you ,0.1 MPaxia shui tong liang chao guo 1200 L·m-2·h-1,fen li xiao lv da yu 98.5%,duo ci xun huan shi yong ,fen li xiao lv da yu 96%。fu ge tu ceng ju you liang hao fang wu sai xing neng ,zai shui tong liang xia jiang qing kuang xia ,yong jiu jing chong xi hou ,shui tong liang ke hui fu dao chu shi zhi 。cai yong di wen shui re ge cheng fa zhi bei yang hua xin tu ceng ,yong TiO2rong jiao duan shao jia gu ,zhi bei chu chao qin shui /shui xia chao shu you ZnO/TiO2fu ge tu ceng bu xiu gang wang ,shui xia lv fang jie chu jiao wei 154.5°±0.8°。TiO2zai ZnOtu ceng biao mian xing cheng yi ceng zhi mi yang hua mo ,di sheng le tu ceng nai suan 、jian fu shi xing neng ,jing suan jian rong ye jin pao 12xiao shi ,reng ju you jiao hao shui xia shu you xing neng 。dui bu tong chong lei shui bao you xing ru hua ye dou you jiao hao fen li xiao guo ,fen li su du kuai ,chong li xia shui tong liang wei 500 L·m-2·h-1zuo you ,0.05 barxia shui tong liang chao guo 1500 L·m-2·h-1,fen li xiao lv da yu 98.5%。ru hua ye suan jian xing dui fen li xiao lv ying xiang jiao xiao ,dan jing suan jian jin pao chu li 12xiao shi hou ,fen li xiao lv jian xiao ,jian xing jin pao hou jian xiao fu du da yu suan xing tiao jian 。fu ge tu ceng dui xie ye zhong gao xie zhi ju you yi ding de fen li xiao guo 。zeng shang ,PPy、WO3/TiO2he ZnO/TiO2fu ge tu ceng bu xiu gang wang ,zhi bei gong yi jian chan 、cheng ben di lian 、mo wu ran ,wei gao xiao 、lu se 、kuai su fen li you shui hun ge wu he shui bao you xing ru hua ye di gong you xiao fang fa ,ji zhong ZnO/TiO2fu ge tu ceng bu xiu gang wang wei shi xian xie zhi fen li di gong ji chu yan jiu 。
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论文详细介绍
论文作者分别是来自中国矿业大学的王博,发表于刊物中国矿业大学2019-07-18论文,是一篇关于涂层论文,水下超疏油论文,水包油型乳化液论文,分离论文,中国矿业大学2019-07-18论文的文章。本文可供学术参考使用,各位学者可以免费参考阅读下载,文章观点不代表本站观点,资料来自中国矿业大学2019-07-18论文网站,若本站收录的文献无意侵犯了您的著作版权,请联系我们删除。
标签:涂层论文; 水下超疏油论文; 水包油型乳化液论文; 分离论文; 中国矿业大学2019-07-18论文;