王浩:Effect of Na3AlF6 Addition and Surface Modification of SiCp on the Microstructure and Mechanical Properties of SiCp/Al Composites论文

王浩:Effect of Na3AlF6 Addition and Surface Modification of SiCp on the Microstructure and Mechanical Properties of SiCp/Al Composites论文

本文主要研究内容

作者王浩(2019)在《Effect of Na3AlF6 Addition and Surface Modification of SiCp on the Microstructure and Mechanical Properties of SiCp/Al Composites》一文中研究指出:Al-matrix composites reinforced with 56.5 vol% SiC were prepared by powder metallurgy with different amounts of additives and surface modifications of SiCp. The crystalline phase, morphology, elements on the surface of SiCp and the interface between SiCp and Al were characterized by XRD, SEM, EDS and EPMA. The results show that it is favorable for the reaction between TiO2-C on the surface of SiCp and Al at the SiCp-Al interface at 1 050 ℃. Besides, the process of Na3AlF6 melting, dissolving and then contacting with Al2O3 formed the NaF-AlF3-Al2O3 system, which generated OAlF2-, promoting the dessolution of Al2O3 film on the surface of Al powder. Na3AlF6 meets the needs of chemical reaction in TiO2-C-Al system at the SiCpAl interface in the way of offering more molten Al. After 0.75 wt% Na3AlF6 was added into raw materials, the whole TiO2-C film and most SiO2 film were destroyed and the interfacial bonding between SiCp and Al was keeping good, in which no obvious void and crack were observed. Meanwhile, no brittle Al4C3 phase formed in the system. At this time, the flexure strength and density of samples presented optimal values, reaching up to 106.5 MPa and 90.77% respectively.

Abstract

Al-matrix composites reinforced with 56.5 vol% SiC were prepared by powder metallurgy with different amounts of additives and surface modifications of SiCp. The crystalline phase, morphology, elements on the surface of SiCp and the interface between SiCp and Al were characterized by XRD, SEM, EDS and EPMA. The results show that it is favorable for the reaction between TiO2-C on the surface of SiCp and Al at the SiCp-Al interface at 1 050 ℃. Besides, the process of Na3AlF6 melting, dissolving and then contacting with Al2O3 formed the NaF-AlF3-Al2O3 system, which generated OAlF2-, promoting the dessolution of Al2O3 film on the surface of Al powder. Na3AlF6 meets the needs of chemical reaction in TiO2-C-Al system at the SiCpAl interface in the way of offering more molten Al. After 0.75 wt% Na3AlF6 was added into raw materials, the whole TiO2-C film and most SiO2 film were destroyed and the interfacial bonding between SiCp and Al was keeping good, in which no obvious void and crack were observed. Meanwhile, no brittle Al4C3 phase formed in the system. At this time, the flexure strength and density of samples presented optimal values, reaching up to 106.5 MPa and 90.77% respectively.

论文参考文献

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  • 论文详细介绍

    论文作者分别是来自Journal of Wuhan University of Technology(Materials Science)的王浩,发表于刊物Journal of Wuhan University of Technology(Materials Science)2019年03期论文,是一篇关于,Journal of Wuhan University of Technology(Materials Science)2019年03期论文的文章。本文可供学术参考使用,各位学者可以免费参考阅读下载,文章观点不代表本站观点,资料来自Journal of Wuhan University of Technology(Materials Science)2019年03期论文网站,若本站收录的文献无意侵犯了您的著作版权,请联系我们删除。

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    王浩:Effect of Na3AlF6 Addition and Surface Modification of SiCp on the Microstructure and Mechanical Properties of SiCp/Al Composites论文
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